Iron oxide density
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Control of morphology and nucleation density of iron oxide nanostructures by electric conditions on iron surfaces exposed to reactive oxygen plasmas
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The possibility to control the morphology and nucleation density of quasi-one-dimensional, single-crystalline nanostructures by varying the electric potential of ironsurfaces exposed to reactive oxygen plasmas is demonstrated experimentally. A systematic increase in the oxygen ion flux through rf biasing of otherwise floating substrates and then an additional increase of the ion/neutral density resulted in remarkable structural transformations of straight nanoneedles into nanowires with controlled tapering/aspect ratio and also in larger nucleation densities. Multiscale numerical simulations relate the microscopic ion flux topographies to the nanostructurenucleation and morphological evolution. This approach is applicable to other metal-oxide nanostructures.
© 2009 American Institute of Physics
Received Tue Apr 28 00:00:00 UTC 2009 Accepted Fri May 08 00:00:00 UTC 2009
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